Journal
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
Volume 98, Issue 6, Pages 1870-1876Publisher
WILEY
DOI: 10.1111/jace.13553
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Funding
- National Natural Science Foundations of China [51002146, 51272242]
- Natural Science Foundations of Beijing [2132050]
- Program for New Century Excellent Talents in University of Ministry of Education of China [NCET-12-0950]
- Beijing Nova Program [Z131103000413047]
- Beijing Youth Excellent Talent Program [YETP0635]
- State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University [KF201306]
- Fundamental Research Funds for the Central Universities [FRF-TP-14-005A1]
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Garnet-type compound Ca3Ga2Ge3O12 and Cr3+-doped or Cr3+/Bi3+ codped Ca3Ga2Ge3O12 phosphors were prepared by a solid-state reaction. The crystal structure of Ca3Ga2Ge3O12 host was studied by X-ray diffraction (XRD) analysis and further determined by the Rietveld refinement. Near-infrared (NIR) photoluminescence (PL) and long-lasting phosphorescence (LLP) emission can be observed from the Cr3+-doped Ca3Ga2Ge3O12 sample, and the enhanced NIR PL emission intensity and LLP decay time can be realized in Cr3+/Bi3+ codped samples. The optimum concentration of Cr3+ in Ca3Ga2Ge3O12 phosphor was about 6mol%, and optimum Bi3+ concentration induced the energy-transfer (ET) process between Bi3+ and Cr3+ ions was about 30mol%. Under different excitation wavelength from 280 to 453nm, all the samples exhibit a broadband emission peaking at 739nm and the intensity of NIR emission increases owing to the ET behavior from Bi3+ to Cr3+ ions. The critical ET distance has been calculated by the concentration-quenching method. The thermally stable luminescence properties were also studied and the introduction of Bi3+ can also improve the thermal stability of the NIR emission.
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