Pulsed field probe of real time magnetization dynamics in magnetic nanoparticle systems

Magnetic nanoparticles (MNPs) are extensively used in biotechnology. These applications rely on magnetic properties that are a keen function of MNP size, distribution, and shape. Various magneto-optical techniques, including Faraday Rotation (FR), Cotton-Mouton Effect, etc., have been employed to characterize magnetic properties of MNPs. Generally, these measurements employ AC or DC fields. In this work, we describe the results from a FR setup that uses pulsed magnetic fields and an analysis technique that makes use of the entire pulse shape to investigate size distribution and shape anisotropy. The setup employs a light source, polarizing components, and a detector that are used to measure the rotation of light from a sample that is subjected to a pulsed magnetic field. This magnetic field snapshot is recorded alongside the intensity pulse of the sample's response. This side by side comparison yields useful information about the real time magnetization dynamics of the system being probed. The setup is highly flexible with variable control of pulse length and peak magnitude. Examining the raw data for the response of bare Fe3O4 and hybrid Au and Fe3O4 nanorods reveals interesting information about Brownian relaxation and the hydrodynamic size of these nanorods. This analysis exploits the self-referencing nature of this measurement to highlight the impact of an applied field on creating a field induced transparency for a longitudinal measurement. Possible sources for this behavior include shape anisotropy and field assisted aggregate formation. (C) 2015 AIP Publishing LLC.