4.5 Article

Sunlight-Driven Synthesis of Triarylethylenes (TAEs) via Metal-Free Mizoroki-Heck-Type Coupling

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2018, Issue 38, Pages 5297-5303

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201800883

Keywords

Metal-free Arylation; Photogenerated intermediates; Triarylethylenes; Sunlight-driven processes; Photochemistry

Funding

  1. Cariplo Foundation
  2. Lombardy Region, Italy [2015-0756]

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A protocol for the preparation of substituted triarylethylenes (TAEs) was developed by using arylazo sulfones as substrates in the presence of 1,1-diarylethylenes. The process took place efficiently in the absence of any (photo)catalyst upon exposure of the reaction mixture to (simulated) sunlight.

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