Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2018, Issue 30, Pages 4113-4120Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201800697
Keywords
Nitrogen heterocycles; Arenes; Benzylation; Copper; Radical reactions; Reaction mechanisms
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Funding
- Department of Henan Province Natural Science and Technology Foundation [172102210225, 172102210222]
- Natural Science Foundation in Henan Province Department of Education [17A150005, 17A150007]
- Program for Innovative Research Team from Zhengzhou [131PCXTD605]
- Project of Youth Backbone Teachers of Henan University of Technology [2016003]
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A novel and efficient approach to the C(sp(2))-H/C(sp(3))-H oxidative coupling of quinoxalin-2(1H)-ones with methylarenes by using Cu-I as catalyst is reported. Various substrates were well tolerated in this methodology and the desired products were given in moderate-to-good yields. This reaction features good functional group compatibility and broad substrate scope.
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