Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2018, Issue 30, Pages 4202-4210Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201800659
Keywords
Fluorinated compounds; Nitrogen heterocycles; Fused-ring systems; Small ring systems; Amino alcohols; Fluorine
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Funding
- Russian Science Foundation [18-13-00136]
- Russian Science Foundation [18-13-00136] Funding Source: Russian Science Foundation
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Fluorinated -bromoenones react readily with amino alcohols containing a secondary amino group to give monocyclic morpholine derivatives or unexpected bicyclic compounds containing a morpholine moiety fused with an oxetane ring. The reactions are highly stereoselective. The assembly of these heterocycles starts with an aza-Michael addition followed by intermolecular substitution and addition processes.
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