Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2018, Issue 35, Pages 4900-4904Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201800849
Keywords
C-C coupling; Iron; Grignard reaction; Radical reactions; Homogeneous catalysis
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Funding
- Spanish MINECO [CTQ2016-79826-R]
- CAM
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An iron-catalyzed Kumada-type cross-coupling reaction of propargyl halides with alkylmagnesium reagents is described. The reaction is fast, takes place in smooth conditions, tolerates several functional groups that would be able to react with the Grignard reagent, and may afford either allene or propargyl coupling derivatives. Factors involved in the observed regioselectivity have been studied.
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