4.5 Article

Nickel-Catalyzed Synthesis of Diaryl Sulfones from Aryl Halides and Sodium Sulfinates

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2018, Issue 10, Pages 1208-1210

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201701478

Keywords

Earth-abundant metals; Nickel; Homogeneous catalysis; Sulfones; Cross-coupling

Funding

  1. Fonds der Chemischen Industrie
  2. Boehringer Ingelheim Foundation
  3. Deutsche Forschungsgemeinschaft (DFG)
  4. China Scholarships Council [201406240029]

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A novel nickel-catalyzed cross-coupling of sulfinic acid salts with aryl halides is described. The reaction provides access to various diaryl sulfones in moderate to excellent yields. A broad range of functional groups and heteroaromatic compounds is tolerated under the reaction conditions.

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