Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2019, Issue 2-3, Pages 309-312Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201800291
Keywords
Trifluoromethylation; Radicals; Alkynes; Fluorinated compounds; Peroxides
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Funding
- Max-Planck-Gesellschaft
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A combination of readily available and bench-stable CF3SO2Na and tBuOOH was efficiently used for hydrotrifluoromethylation of alkynes. An excellent trans-selectivity was demonstrated in the synthesis of alkenes. The developed mild reaction conditions allow the supression of the competing Meyer-Schuster-type rearrangement.
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