4.1 Article

Synthesis of antipodal β-trisubstituted meso-tetraphenylporphyrins and the crystal structure of hexaphenylporphinatozinc(II) bispyridinate complex

Journal

JOURNAL OF CHEMICAL SCIENCES
Volume 127, Issue 4, Pages 663-670

Publisher

INDIAN ACAD SCIENCES
DOI: 10.1007/s12039-015-0821-2

Keywords

Synthesis; beta-pyrrole trisubstituted porphyrins; substituted porphyrins; metalloporphyrins; hexaphenylporphyrin; crystal structure

Funding

  1. Council of Scientific and Industrial Research (Governemt of India)

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A series of antipodal beta-trisubstituted meso-tetraphenylporphyrins, H2TPP(R)(3) (R = CH3, Ph, PE, and 2(')-thienyl) derivatives and their metal (Cu(II) and Zn(II)) complexes were synthesised and characterised by electronic absorption, H-1 NMR spectroscopy and mass spectrometry. The magnitude of the red-shift in absorption bands in these free-base porphyrins depend on the nature of the substituent and follow the general trend: PE > 2(')-thienyl > Br > Ph > CH3. Synthesis, characterisation and crystal structure of 2,5,10,12,15,20-hexaphenylporphinato zinc(II) bispyridinate, ZnTPP(Ph)(2)(Py)(2) complex is also reported. It shows planar geometry of the porphyrin ring with two beta-phenyls located at the antipodal 2,12-pyrrole positions. The two axially coordinated pyridine ring planes are oriented almost parallel to each other and they are in staggered conformation relative to opposite pyrrolic nitrogens. The normal-coordinate structural decomposition analysis of the ZnTPP(Ph)(2)(Py)(2) complex revealed slight wave distortion of the macrocycle.

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