Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 20-21, Pages 2241-2246Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201800330
Keywords
Cage compounds; Ketones; Cyclopentadienyl ligands; Oxido ligands; Redox chemistry
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Funding
- Australian Research Council (ARC Discovery) [DP 160101640]
- Australian Postgraduate Award
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The 9-fluorenone (fn) ketyl in [Yb-III(DippForm)(2)(fn-O)] {DippForm = N,N-bis(2,6-diisopropylphenyl)formamidinate}, underwent reduction to the dianion ({C13H8}-O) upon single electron transfer from (SmI2)-I-II(thf)(2). The dianion was obtained as a decanuclear, deca-9-fluorenolato, tetraoxido mixed-oxidation-state samarium cage [Sm10O4{(C13H8)-O}(10)(thf)(10)], obtained after ligand redistribution. The structure is relevant to the deoxygenation of ketones by lanthanoid metals.
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