4.5 Article

Dehydration of ortho-, meta- and para-Alkoxy Phenylboronic Acids to their Corresponding Boroxines

Journal

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 13, Pages 1492-1498

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201701485

Keywords

Phenylboronic acid; Alkoxy; Isomers; Acidity; DSC; TGA; Boroxines; X-ray diffraction

Funding

  1. Polish Ministry of Science and Higher Education
  2. Ministry of Education, Youth and Sport of the Czech Republic [7AMB16PL061]
  3. Czech Science Foundation [17-00289Y]
  4. Faculty of Chemistry, Warsaw University of Technology
  5. Polish National Science Center (NCN) [UMO-2016/20/T/ST5/00374]

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Isomeric isobutoxy phenylboronic acids (ortho-, meta-, para-) were synthesized and their properties such as pK(a) and thermal stability have been compared. Molecular and crystal structures of the para isomer were determined by single crystal XRD methods. DSC and TGA measurements have been carried out on all isomers to study their dehydration as well as thermal stability. The results show that the position of the substituent in phenylboronic acids influences their acidity as well as possible formation of the corresponding boroxines.

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