Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 13, Pages 1533-1539Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201701270
Keywords
Hydrothermal synthesis; Carbon; Nanostructures; Electrochemistry; Lithium-ion batteries
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Funding
- National Natural Science Foundation of China [61274004, 51232006, 51201037]
- National High Technology Research and Development Program (863 Program) of China [2013AA032002]
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Monodispersed single-crystalline LiMnPO4 nanobelts and nanorods were successfully prepared by a simple hydrothermal method. On the basis of the experimental results, a possible mechanism for the formation of the monodispersed LiMnPO4 nanobelts and nanorods was proposed. Compared with our previously proposed flowerlike, stamenlike LiMnPO4/C nanostructures self-assembled with (010) nanosheets and [001] nanorods, the corresponding monodispersed nanoparticles show enhanced electrochemical performances due to the full carbon coating along the surface. Moreover, because of the narrowed size along [100], the LiMnPO4@C nanorods exhibit a much higher discharge capacity compared with that of the LiMnPO4@C nanobelts.
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