Occurrence, distribution and risk of organophosphate esters in urban road dust in Beijing, China

As a major group of plasticizers and flame-retardants, organophosphate esters (OPEs) have attracted particular attention due to their wide occurrence and potential impacts on human health and ecosystems. In the present study, the occurrence and distribution of 14 OPEs, including seven Alkyl-OPEs, three CI-OPEs, and four Aryl-OPEs, were investigated in 65 road dust samples collected from November to December 2014 in Beijing, China. CI-OPEs were the predominant compounds in the road dust samples, with the median concentration of 646 mu g/kg, followed by the Alkyl-OPEs (median 135 mu g/kg) and Aryl-OPEs (median 129 mu g/kg). Tris(2-chloro-l-methylethyl) phosphate (TCPP) was the most abundant OPE with the median concentration of 384 mu g/kg. In addition, OPEs levels showed significant difference (p < 0.05) in the spatial distribution. Markedly higher levels of OPEs were observed in 2nd and 3rd ring road with heavy traffic and high population density, indicating that the traffic and population were important factors for this distribution pattern. It was further supported by the analysis of OPEs in roadside soil and indoor dust in the vicinity of road dust sample sites. Finally, the average daily dose (ADD) for OPEs via inhalation, dermal absorption, and ingestion was calculated to evaluate the carcinogenic and non-carcinogenic risks to residents exposed to OPEs in the road dust. Risk assessment revealed that the risk originating from exposure to OPEs of road dust is currently low in Beijing, China. (C) 2018 Elsevier Ltd. All rights reserved.