Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 29, Pages 10278-10288Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201500545
Keywords
CH activation; fluorenes; homogeneous catalysis; polycyclic aromatic hydrocarbons; transition metals
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Funding
- Natural Science Foundation of China [1601310045, 21102119, 21272191]
- Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT)
- Jiangsu University Foundation [1281310043]
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Fluorenes are a commonly encountered structural motif in materials science, pharmaceutical chemistry, and organic synthesis. Among various strategies towards the synthesis of this unique structure, transition metal-catalyzed functionalization has emerged as one of the most efficient methods. This Minireview presents an overview of the recent advances in this emerging area by highlighting the reactions' specificity and applicability and, where possible, provides a mechanistic rationale.
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