Journal
ENERGY & ENVIRONMENTAL SCIENCE
Volume 11, Issue 7, Pages 1717-1722Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ee00365c
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Funding
- German Research Foundation (DFG) within the Cluster of Excellence 'Center for Advancing Electronics Dresden' (cfaed)
- Initiative and Networking Fund of the German Helmholtz Association
- International Helmholtz Research School for Nanoelectronic Networks NanoNet [VH-KO-606]
- ERC Grant on 2DMATER
- EU Graphene Flagship
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Efficient thermal protection is of great significance for electronic devices. Herein, we demonstrate a novel thermoswitchable microsupercapacitor (TS-MSC) with the self-protection function utilizing the thermodynamic behavior of a smart electrolyte, a lithium saltdissolved polymer sol, poly(N-isopropylacrylamide)-g-methylcellulose. Benefiting from the reversibility of ionic conductivity, the TS-MSC exhibited a broad temperature window (30-80 degrees C) and totally switch-off behavior at 80 degrees C, as well as excellent cycling stability upon heating/cooling cycles. In addition, the thermal protection of on-chip integrated MSCs in series or parallel was achieved by controlling a single TS-MSC connected with a computer CPU under different working conditions. Therefore, TS-MSCs are promising components in the thermal protection of practical on-chip electronic devices.
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