Journal
RSC ADVANCES
Volume 5, Issue 76, Pages 62167-62172Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra09595f
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Funding
- DST, India [SR/FT/CS-96/2011]
- Indian School of Mines Dhanbad [FRS/31/2012-13/AC]
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Three lanthanide(III) morpholine 4-dithiocarbamate complexes [Ln(Phen)(Mph-Dtc)(3)]center dot xCH(2)Cl(2) [Ln = Pr (1), Nd (2) and Eu (3); Mph-Dtc = morpholine 4-dithiocarbamate; x = 2 (1) or 1 (2, 3)] have been prepared from the reaction of the potassium salt of morpholine 4-dithiocarbamate with lanthanide nitrates and phenanthroline. Complexes 1-3 were characterized by various analytical techniques and their solid state structures were established by single crystal X-ray diffraction analysis. The Ln(III) ions are nine or eight coordinated in 1 and 2, 3 respectively. Interestingly, oxygen atom of one of the three coordinated Mph-Dtc ligands is further coordinated to a Pr(III) ion of the adjacent molecule. Thus, it results in the formation of an one-dimensional (1D) polymeric structure. Thermal stability and optical properties of 1-3 have been investigated.
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