4.7 Article

The mechanism of the terahertz spectroscopy for oil shale detection

Journal

ENERGY
Volume 161, Issue -, Pages 46-51

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.energy.2018.07.112

Keywords

Oil shale; Terahertz spectroscopy; Aliphatic compounds; Kerogen

Funding

  1. National Nature Science Foundation of China [11574401]
  2. Science Foundation of China University of Petroleum, Beijing [2462017YJRC029, 2462018BJC005, yjs2017019]
  3. Beijing Natural Science Foundation [1184016]

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Terahertz time domain spectroscopy (THz-TDS) can directly detect oil shales. The absorption coefficient is related to the oil content in the rock. This value can be compared across regions to measuring the oil content in the oil shale. Here we studied three regions and included scanning electron microscope (SEM) and thermogravimetric analysis (TGA) to verify the amount of kerogen within oil shale prior to the constitution of the mineral matrix via the THz response. Aromatic and the aliphatic compounds contribute to the absorption of shales in the THz range due to the relatively high intramolecular interactions this reveals the mechanism of THz radiation penetration through shales as reported in previous reports. The differences in quantum structure of a molecule between organic and inorganic materials suggest that THz-TDS can be applied to geophysical prospecting and improve the effectiveness of the detection of organics in oil shale. (C) 2018 Elsevier Ltd. All rights reserved.

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