Oxygen-deficient tungsten oxide nanorods with high crystallinity: Promising stable anode for asymmetric supercapacitors

Asymmetric supercapacitors (ASCs) represent an effective electrochemical energy storage device with wider potential windows, which may lead to a substantial increase in the energy density and power density of the device. Unfortunately, their development is severely restricted by the carbon-based negative electrodes with low energy density. In this work, we demonstrate the facile synthesis of engineering WO3-x electrode on carbon cloth via hydrogenation, which achieves excellent electrochemical performance as a negative electrode for ASCs. The enhanced crystallinity and introduction of oxygen vacancy synergistically contribute to more reversible redox reactions, faster ion diffusion and charge transfer rates. The as-obtained WO3-x electrode reaches a high areal capacitance of 1.83 Fcm(-2) at 1 mAcm(-2), and an outstanding electrochemical durability with high capacity retention of 74.8% after 10000 cycles. All these results open a new way to the construction of high-performance anodes for ASCs. (C) 2018 Elsevier Ltd. All rights reserved.