Journal
ELECTROCHIMICA ACTA
Volume 283, Issue -, Pages 538-547Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.06.043
Keywords
Supercapacitors; Ordered macro-porous electrode plate; Energy storage; Core-shell structure; Hybrid device
Categories
Funding
- Research Institute for Sustainable Urban Development, The Hong Kong Polytechnic University
- National Key R&D Program of China [2016YFE0102300]
- City University of Hong Kong Strategic Research Grant (SRG) [7004644]
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Multidimensional CoMoO4@Ni(OH)(2) nanocomposite materials are fabricated on the nickel modified surface and channels of an ordered macro-porous electrode plate (OMEP) by a multistep high temperature hydrothermal method as the supercapacitor electrode in a high power density energy storage device. The effects, morphology, capacitive properties, and formation mechanism of the CoMoO4@Ni(OH)(2) composite materials are systematically investigated. Compared to nanostructured nickel grown on the OMEP or CoMoO4@Ni(OH)(2) on nickel plate with the same area, the CoMoO4@Ni(OH)(2)/OMEP shows enhanced electrochemical energy storage properties such as high energy capacitance of 8.55 F cm(-2) (1812.42 Fg(-1)) at 2 mA cm(-2) and good cycling stability of 87.42% capacity retention after 5000 cycles. An asymmetrical supercapacitor (ASC) device is assembled with a polyethylene (PE) membrane, CoMoO4@Ni(OH)(2)/OMEP, and active carbon covered nickel foam. The ASC with the CoMoO4@Ni(OH)(2)/OMEP has an energy density of 9.66 Wh Kg(-1) even at a power density of 3000 W Kg(-1) as well as stable power characteristics with 86.5% retention after 10,000 cycles at a current of 0.06 A. The device produces large instantaneous power after charging at 2.8 V for 10 s one ASC can power a 5 mm red LED with high efficiency. (C) 2018 Elsevier Ltd. All rights reserved.
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