4.6 Article

High-performance flexible-film supercapacitors of layered hydrous RuO2/poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) through vacuum filtration

Journal

ELECTROCHIMICA ACTA
Volume 283, Issue -, Pages 744-754

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.06.044

Keywords

Miniaturized supercapacitors; Hydrous RuO2 nanoparticles; PEDOT-PSS; Flexible layered films; Vacuum filtration

Funding

  1. National Natural Science Foundation of China [51662012, 51572117, 51463008]
  2. Natural Science Foundation of Jiangxi Province [20171BAB206013]
  3. Jiangxi Outstanding Young Talent Fund Projects [20171BCB23076]
  4. Innovation Driven 5511 Project of Jiangxi Province [20165BCB18016]
  5. Scientific Research Projects of Jiangxi Science and Technology Normal University [2016QNBJRC001]
  6. Jiangxi Provincial Department of Education [GJJ160762]
  7. Jiangxi Science & Technology Normal University Innovation Fund of Postgraduates [YC2017-X34]

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A micron-thick flexible layered RuO2 center dot 1.18H(2)O/PED0T-PSS film with high electric conductivity of about 306 S cm(-1) (sheet resistance of film of 7.1 Omega sq(-1)) was prepared using commercial PEDOT-PSS dispersion and RuO2 center dot 1.18H(2)O nanoparticles through a simple, low-cost vacuum filtration technology. The layered flexible film could be used as a rope to hang up 300 gram weight and as a conducting wire in a circuit to light a blue LED lamp. The symmetrical supercapacitor based on the layered flexible films showed high specific capacitance of 591 Fg(-1) (volumetric specific capacitance of 530 F cm(-3)) at 10 mV s(-1), excellent long-term cycling stability (capacitance retention of 91.5%) after 5000 cycles, and high energy density of 18 Wh kg(-1) at high power density of 5000 W kg(-1). The flexible film as function as current collector and active material simultaneously will have practical application in miniaturized flexible supercapacitors. (C) 2018 Elsevier Ltd. All rights reserved.

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