Journal
ELECTROCHIMICA ACTA
Volume 277, Issue -, Pages 143-150Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.05.009
Keywords
Manganese oxides; Phosphate doping; Bifunctional; Oxygen electrocatalyst
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Funding
- National Research Foundation (NRF), Prime Minister's office, Singapore, under the Campus for Research Excellence and Technological Enterprise (CREATE) program
- Advanced Energy Storage Program of the Science and Engineering Research Council (SERC), Singapore [R-265-000-436-305]
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The search for low cost and high activity bifunctional electrocatalysts for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) is a research priority in the development of rechargeable metal-air batteries. Manganese oxides are the current favorite, but their native activity needs to be substantially improved before they can be considered as the substitute of noble metals. We discovered phosphate modification as an effective strategy to increase the bifunctional oxygen activity of MnO2 in ORR and OER. Specifically, the half-wave potential of phosphate-promoted alpha-MnO2 (PMO) for ORR is 0.85 V vs. RHE, similar to 70mV more positive than alpha-MnO2 and the same as the benchmark 20 wt% Pt/C catalyst. The OER potential to maintain 10 mAcm(-2) of current density is 1.63 V, similar to 40 mV more negative than alpha MnO2 and about the same as the benchmark 20 wt% Ir/C catalyst (1.60 V). The potential difference between ORR (at -3mAcm(-2)) and OER (at 10mA cm(-2)) is 0.79 V, a standard measure of bifunctional oxygen activity, notably surpasses the performance of a-MnO2 (0.91 V) and the noble metals (0.95 V for Pt/C and 0.93 V for Ir/C). Additional electrochemical measurements and density functional theory calculations suggest that the promoted bifunctional activity of PMO is due to the dual-affinity of phosphate for O and OH groups, which assists O-2/OH adsorption in ORR/OER. (C) 2018 Elsevier Ltd. All rights reserved.
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