4.6 Article

Flexible supercapacitors based on a ternary composite of polyaniline/polypyrrole/graphite on gold coated sandpaper

Journal

ELECTROCHIMICA ACTA
Volume 274, Issue -, Pages 200-207

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.04.063

Keywords

Supercapacitors; Hierarchical structures; Polyaniline; Polypyrrole

Funding

  1. FINEP
  2. CAPES
  3. FAPESB
  4. FACEPE
  5. CNPq

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Developing low-cost and efficient flexible supercapacitors is an important step towards the production of new energy storage systems for efficient wearable electronic devices. In this work, we report a simple and cost-effective approach to produce flexible electrodes for supercapacitors. The system consists of a complex ternary structure of hierarchical polyaniline (PAn) assembled on a polypyrrole (PPy) layer deposited on graphite pencil traces (Grt) in sandpaper. The proposed ternary composite PAn-PPy-Grt-Sp assembled in a device offered a maximal areal capacitance of 55.35 mF cm(-2) at 0.3 mA cm(-2), a higher value when compared to its counterparts of PAn-Grt-Sp (31.8 mF cm(-2)) and PPy-Grt-Sp (19.75 mF cm(-2)). The ternary composite also exhibited a higher energy (4.92 mu Wh cm(-2)) and power density (87.09 mu Wcm(-2)) at a current density of 0.3 mA cm(-2) producing a more equilibrated supercapacitor device. The response to mechanical efforts returned negligible variation in electrochemical properties while cyclability remains as 80% of initial value after 3000 cycles. (c) 2018 Elsevier Ltd. All rights reserved.

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