4.6 Article

Coral-like Cu-Co-mixed oxide for stable electro-properties of glucose determination

Journal

ELECTROCHIMICA ACTA
Volume 273, Issue -, Pages 502-510

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.04.003

Keywords

Spinel; Coral-like; CuCo2O4; Glucose; Sensor

Funding

  1. National Natural Science Funds [51521061]
  2. State Key Laboratory of Solidification Processing in NWPU [142-TZ-2016]
  3. Seed Foundation of Innovation and Creation for Graduate Students in Northwestern Polytechnical University [Z2017009]

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Nanowire-constructed coral-like spinel Cu-Co-mixed oxides were synthesized via hydrothermal reaction. Owing to the unique nanoarchitecture, the Cu-Co-O provide abundant electro-active sites and channels for ions transfer. And also because of the synergistic effect of copper and cobalt ions in the spinel crystal, the electrode modified with the Cu-Co-O material shows prominent electrocatalytic performance toward the oxidation of glucose. The rapid amperometric response to glucose was observed with a high sensitivity (8838.26 mA cm(-2)mM(-1)), low detection limit (0.5 mmol/L) and fast response (within 1 s). The mild synthesis method and outstanding electrocatalytic performance make it promising for the reliable and durable determination of glucose. (c) 2018 Elsevier Ltd. All rights reserved.

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