Journal
ELECTROCHIMICA ACTA
Volume 269, Issue -, Pages 676-685Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2018.03.012
Keywords
All-carbon supercapactior; Porous carbon; High-rate capability; Binder-free; Charge-discharge capability
Categories
Funding
- National Science Foundation of China [51275195]
- National Basic Research Program of China [2015CB057205]
- Program for Changjiang Scholars and the Innovative Research Team in University [IRT13017]
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Fast charge-discharge capability even at high current densities is desired for supercapacitors. One-step simple synthesis using sol-gel method is used to fabricate binder-free activated carbon electrode, where KOH was used to tune the porosity of electrode. The gravimetric capacitance of the optimized electrode is up to 272 F g(-1) at a current density of 1 A g(-1). More importantly, 75.9% gravimetric capacitance retention is kept at an ultrahigh current density of 50 A g(-1). Furthermore, a symmetrical supercapacitor device is assembled in 1 M Et4NBF4 in acetonitrile, which delivers an energy density of 18-25 W h kg(-1). Apparently, the carbon material with open rich pores provides short ion diffusion pathways for energy storage and the binder-free method guarantees high conductivity of the whole system, leading to high-rate performance. The porous carbon structure as well as the low-cost and simple design paves the way for fabricating supercapacitors with enhanced rate capability. (c) 2018 Elsevier Ltd. All rights reserved.
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