4.6 Article

MnO2-CoP3 nanowires array: An efficient electrocatalyst for alkaline oxygen evolution reaction with enhanced activity

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 86, Issue -, Pages 161-165

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2017.12.008

Keywords

MnO2-CoP3; Nanowires array; Electrocatalyst; Water oxidation; Alkaline solution

Funding

  1. National Natural Science Foundation of China [21575137]

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It is highly desired to enhance the catalytic activity of MnO2 for the oxygen evolution reaction (OER) in alkaline media. Herein we report the development of MnO2-CoP3 nanowires array on Ti mesh (MnO2-CoP3/Ti) as an efficient 3D OER electrocatalyst with good stability under basic conditions. In 1.0 M KOH, the MnO2-CoP3/Ti requires a current density of 10 mA cm(-2) at overpotential of only 288 mV, which is 120 mV less than that for MnO2/Ti. In addition, such MnO2-CoP3/Ti also exhibits high long-term electrochemical durability.

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