Journal
ELECTROANALYSIS
Volume 30, Issue 7, Pages 1536-1544Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201800128
Keywords
Conductivity; ion-exchange membrane; solid contact potentiometry; wearable sensor
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Funding
- Ramon y Cajal Programme
- Spanish ministry of Economy and Competitiveness
- European Regional Development Fund (ERDF) [CTQ2013-46404-R, CTQ2016-77128-R]
- FPI scholarship [BES-2014-067661]
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A sensor for monitoring total ion activity is described, and its performance as a wearable device for monitoring the total ion levels of sweat is evaluated. The sensor works by tracking changes in the Donnan potential generated across a Nafion (R) membrane. This cation-exchange polymer was cast on a paper coated with carbon-ink, making the platform elegantly simple. Analytical parameters during calibration in aqueous solution include a sensitivity of 56.3 +/- 1.0mV/dec.a((Na+)) and a standard deviation between standard electrode potentials of 5.3mV (N=5) for first time use. By integrating a paper-based pseudo-reference electrode, a miniature disposable electrochemical cell (the IonSens device) was created and demonstrated as a wearable sensor. Potentiometric measurements estimating the total ion activities were validated against conductivity measurements. Recoveries of eleven raw sweat samples were determined to be 95.2 +/- 6.6% (n=3). The perspiration conductivity profile of an athlete during exercise was monitored in real-time and visualized on a mobile phone application connected via Bluetooth (R). The excellent reproducibility of the electrode without any conditioning is noteworthy and lends itself to applications including - but not limited to - the monitoring of total ion activity in sweat.
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