Journal
DYES AND PIGMENTS
Volume 156, Issue -, Pages 233-242Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2018.03.006
Keywords
Acidochromic; Dipyrrolopyrazine; Intramolecular charge transfer; Donor-pi-Acceptor
Funding
- Bio & Medical Technology Development Program of the National Research Foundation - Ministry of Science, ICT & Future Planning [2014M3A9A9073847]
- Ministry of Trade, Industry Energy
- Korea Institute for Advancement of Technology [M0000338]
- Korea Evaluation Institute of Industrial Technology (KEIT) [M0000338] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2014M3A9A9073847] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A practical approach towards the development of organic scaffold for material science application through substituent engineering of dipyrrolopyrazine (DPP) chromophore has been introduced. We describe the synthesis and optoelectronic characterization of DPP-derivatives decorated with Donor and acceptor moieties. This study showed that tailoring of the optical properties in the desired direction can be achieved by differing electron donor and acceptor units attached at C-2 and C-6 position of DPP scaffold. The optical, thermal, and electrochemical properties have been investigated. Chromophores exhibit red-shift in absorption and emission spectra upon treatment with TFA and also exhibit distinct self-assembly behaviour. Morphological characterizations indicate the formation of nanorods and microrods. Optical, thermal and morphological studies indicate its potential application in sensors and other optoelectronic device.
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