Journal
DALTON TRANSACTIONS
Volume 47, Issue 27, Pages 8879-8883Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt01993b
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Funding
- EPSRC [EP/M027732/1]
- University of Oxford
- Elemental Microanalysis Ltd (Devon)
- EPSRC [EP/M027732/1] Funding Source: UKRI
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The synthesis of a novel heterocubane [RSnE](4) was successful for E = As, while for E = P differing behaviour was observed. Aryl-substituted chlorostannylenes were treated with salts of heavy cyanate homologues PCO- and AsCO-. The reaction with AsCO- salts afforded primarily [TerSnAs](4) (Ter = 2,6-dimesitylphenyl). In contrast, the reaction of TerSnCl with NaPCO proceeded considerably less cleanly affording a mixture of products. The main product was putatively a neutral [Ter(4)Sn(4)P(4)] compound, however, it is not a cubane. A variety of by-products of this reaction could be characterised crystallographically.
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