Journal
DALTON TRANSACTIONS
Volume 47, Issue 25, Pages 8189-8192Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt01406j
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- U.S. Department of Energy, Office of Science, Early Career Research Program [DE-SC-0014174]
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The first uranium(iii) phosphido complex is reported. The reaction of (C5Me5)(2)UI(THF) with KP[(C6H2Me3-2,4,6)(SiMe3)] affords (C5Me5)(2)U[P(C6H2Me3-2,4,6)(SiMe3)](THF), 1. The reactivity of 1 was explored with two equivalents of N3SiMe3 and N(3)Ad, Ad = adamantyl, both of which produce U(VI) bis(imido) complexes via four-electron reduction of the azides.
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