4.7 Article

Boron-based donor-spiro-acceptor compounds exhibiting thermally activated delayed fluorescence (TADF)

Journal

DALTON TRANSACTIONS
Volume 47, Issue 31, Pages 10394-10398

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt01255e

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Funding

  1. state of Baden-Wurttemberg through bwHPC
  2. Deutsche Forschungsgemeinschaft DFG [LO2167/1-1, INST 40/467-1]
  3. German Excellence Initiative via the Young Scholar Fund of the University of Konstanz [83943218]

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Four boron-based donor-spiro-acceptor compounds, composed of different donor moieties and borylated 2-phenylpyridines as the acceptor, were studied. Their intense photoluminescence in the solid state can be tuned by changing the donor and long emission lifetimes on the microsecond scale indicate thermally activated delayed fluorescence (TADF).

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