Journal
DALTON TRANSACTIONS
Volume 47, Issue 15, Pages 5166-5170Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt00335a
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Funding
- Application Basis Research Project of Yunnan Province Science and Technology Department [2017FD144]
- National Natural Science Foundation of China [51764048, 51474191]
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Herein, an excellent anode was achieved for a lithium-ion battery based on a polyoxometalate-organic framework [Ni-5(OH)(3)(trzS)(3)(en)(H2O)(B-alpha-PW9O34)] for the first time. It can deliver a capacity of 710 mA h g(-1) at 100 mA g(-1) after 50 cycles and a high capacity retention of 82.2% after 500 cycles at a high rate of 800 mA g(-1), which is supposed to be due to the unique porous characteristic and high chemical stability of the proposed anode. The higher capacity was ascribed to Ni and W of the building unit taking part in lithium storage.
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