Journal
DALTON TRANSACTIONS
Volume 47, Issue 12, Pages 4228-4235Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt04675h
Keywords
-
Categories
Funding
- La Trobe University
- La Trobe Institute of Molecular Sciences
- ARC [FT16010007]
Ask authors/readers for more resources
A novel synthetic approach for the synthesis of gold(iii) acetato, alkoxolato and alkynyl complexes was developed via the reactivity of gold(iii) trications containing the N,N-chelating ligand 2,2-bipyridine and N,N,N-chelating ligand terpyridine through direct reactions with the protic precursors. This protocol avoids the gold(iii) chloride bond activation pathway commonly employed to access these functionalities. For example exposure of [LAu(iii)L]OTf3 (L = N,N,N-terpyridine, L = 4-DMAP) to RH (R = OCH3, OAc, Ph-?) results in the facile formation of the corresponding functionalised gold(iii) complexes [LAu(iii)R]OTf2.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available