4.7 Article

Unified meso-pores and dense Cu2+ sites in porous coordination polymers for highly efficient gas storage and separation

Journal

DALTON TRANSACTIONS
Volume 47, Issue 13, Pages 4424-4427

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt00512e

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Funding

  1. National Natural Science Foundation of China [21671102]
  2. Natural Science Foundation of Jiangsu Province [BK20161538]
  3. Ministry of Education of China [IRT13070]
  4. Six Talent Peaks Project in Jiangsu Province [JY-030]
  5. State Key Laboratory of Materials-Oriented Chemical Engineering [ZK201406]
  6. State Key Laboratory of Coordination Chemistry [SKLCC1616]

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Unified meso-pores and dense open metal sites (OMS) in porous coordination polymers (PCPs) allow highly promising H-2 and C2-hydrocarbon storage, as well as rapid and efficient C2H2/4 enrichment from CO2 mixtures. The positive function of the OMS, associated with guest thermodynamics, was well revealed by in situ infrared (IR) spectroscopy study.

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