Journal
CRYSTENGCOMM
Volume 20, Issue 39, Pages 5929-5934Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ce00702k
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Funding
- Johns Hopkins University, Krieger School of Art and Sciences, Faculty Innovation Award
- NSF, Division of Materials Research (DMR), Solid State Chemistry (SSMC) CAREER grant [DMR-1253562]
- David and Lucile Packard Foundation
- Sloan Research Fellowship
- UT-Battelle, LLC [DE-AC05-00OR22725]
- National Science Foundation [DMR-1539918]
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We report the successful crystal growth of a previously unknown mixed-metal organic compound (CH3NH3)(2)AgInBr6. This phase, which is not obtained by direct combination of reactants, is crystallized through the use of Pb2+ (from CH3NH3PbBr3) to modulate the soluble intermediates and force formation of (CH3NH3)(2)AgInBr6. Our results provide insights into mechanism and design-driven crystal growth and discovery of new halide materials that are chemically related to perovskites with photovoltaic and related applications.
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