4.7 Article

Defect-related anisotropic surface microstructures of nonpolar a-plane GaN epitaxial films

Journal

CRYSTENGCOMM
Volume 20, Issue 9, Pages 1198-1204

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ce02121f

Keywords

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Funding

  1. National Natural Science Foundation of China [51702102, 51572091, 51372001]
  2. National Science Fund for Excellent Young Scholars of China [51422203]
  3. Outstanding Youth Foundation of Guangdong Scientific Committee [S2013050013882]
  4. Natural Science Foundation for Doctor Start of Guangdong Province [2017A030310518]
  5. Postdoctoral Science Foundation of China [2017M610520]
  6. Key Project in Science and Technology of Guangdong Province [2014B010119001, 2014B010121004, 2011A080801018]
  7. Strategic Special Funds for LEDs of Guangdong Province [2011A081301010, 2011A081301012, 2012A080302002]
  8. Key Project in Production and Research Collaborative Innovation of Guangzhou City [201604046027]

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The anisotropic surface etching behavior of nonpolar a-plane GaN (11 (2) over bar0) epitaxial films, grown by pulsed laser deposition, was investigated experimentally by wet chemical etching. Crystal-orientation dependent face state, induced by anisotropic growth kinetics, is the origination of the anisotropic properties of the a-plane GaN epitaxial films. Defects that propagate into the surface offer initial positions for the etching process. A joint effect of two factors determines the etching-exposed surface morphology, primarily including triangular prisms and pits, thus making wet chemical etching a promising tool for the investigation of defect distribution. Type I-1 basal stacking faults and partial dislocations are proven to have a direct connection with etching-exposed triangular prisms and pits, respectively. This study presents a mechanism research from the standpoint of the evolution process of the surface morphology during the etching process and brings insight for further understanding of the anisotropic properties of the nonpolar GaN epitaxial films for the realization of a high polarization light-emission device, which has a broad application in display and backlighting.

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