4.7 Article

Large volumetric thermal expansion of a novel organic cocrystal over a wide temperature range

Journal

CRYSTENGCOMM
Volume 20, Issue 5, Pages 631-635

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ce01848g

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Funding

  1. National Research Foundation
  2. Department of Science and Technology (SARCHI Program)
  3. Stellen-bosch University
  4. UMYU (TETFund)
  5. Claude Leon Foundation

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An organic cocrystal consisting of 4-aminobenzonitrile and 4-(dimethylamino) benzonitrile (ABN.2DMABN) undergoes positive linear thermal expansion along its three principal axes over the temperature range 100-300 K. The associated volumetric thermal expansion coefficient is the largest reported to date for a cocrystal in the wide temperature range investigated.

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