Journal
CRYSTAL GROWTH & DESIGN
Volume 18, Issue 4, Pages 1931-1934Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.7b01701
Keywords
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Funding
- National Natural Science Foundation of China [21701091, 21622607, 21761132009]
- K. C. Wong Magna Fund in Ningbo University
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A twofold interpenetrated three-dimensional iron coordination polymer with PtS-type topology, Fe (NCS)(2)(TINM)center dot 1/2TINM (1, TINM = tetrakis(isonicotinoxymethyOmethane), constructed by a semirigid tetradentate ligand, displays an incomplete spin-crossover behavior with T-1/2 at 118 K. Furthermore, the correlation between the external -pressure and spin transition is also discussed following theoretical approaches.
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