4.7 Article

Corrosion of copper in pure O2-free water?

Journal

CORROSION SCIENCE
Volume 137, Issue -, Pages 1-12

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2018.02.008

Keywords

Copper; Corrosion; Water; Hydrogen

Funding

  1. Swedish Nuclear Fuel and Waste Management Co., SKB

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Copper exposed to pure, O-2-free water for several months in glass- and metal-contained, well-controlled systems shows no evidence of corrosion, either through hydrogen evolution or through the occurrence of oxidized copper. The results contradict the interpretation of recent experiments where it has been claimed that copper corrodes in pure, O-2-free water far above the very limited extent predicted by established thermodynamic data. Reasons for the different experimental outcomes are discussed. Experimental and theoretical efforts to identify hitherto unknown, potentially corrosion driving species of the Cu-O-H system and studies of copper/water surface reactions are reviewed as background for the present study.

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