Journal
COORDINATION CHEMISTRY REVIEWS
Volume 355, Issue -, Pages 150-172Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2017.08.004
Keywords
Hemilabile ligands; Variable coordination modes; Xantphos; DPEphos; POP ligands; Catalysis
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Funding
- EPSRC [EP/M024210]
- University of Oxford
- Engineering and Physical Sciences Research Council [EP/M024210/1, 1513226] Funding Source: researchfish
- EPSRC [EP/M024210/1] Funding Source: UKRI
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Hemilabile ligands ligands containing two or more potential donors to a metal centre, of which one or more can dissociate have the ability to provide a transition metal complex with open coordination sites at which reactivity can occur, or stabilise low coordinate intermediates along reaction pathways. POP type ligands and in particular POP, Xantphos, DBFphos and DPEphos-based ligands contain three possible binding sites: two phosphines and an ether linker, thus have the potential to show kappa(1)-, kappa(2)- or kappa(3)-binding modes. This review summarises the examples where POP-type ligands display hemilabile, or closely related variable coordination, characteristics in either synthesis or catalysis. (C) 2017 The Authors. Published by Elsevier B.V.
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