Journal
COORDINATION CHEMISTRY REVIEWS
Volume 372, Issue -, Pages 1-30Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2018.05.024
Keywords
Poly(tetrazole) ligand; Coordination polymer; Metal-organic framework; Synthesis; Crystal structure; Functional properties
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Funding
- University of Insubria
- University of Camerino
- University of Galati
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In the past two decades the chemistry of coordination polymers (CPs) and metal-organic frameworks (MOFs) has known an incessant development at both the academic and industrial level: the diversity they show in chemical composition, structural features and chemico-physical properties makes them attractive for a wide range of applications of technological, economical and/or environmental interest. Within this scenario, this review focuses the attention on the transition-metal-ion CPs and MOFs built up with bis-, tris- and tetrakis(5-substituted tetrazolate) ligands. After a short introduction on CPs and MOFs, and the chemistry of tetrazole and its derivatives, the reader is provided with a brief description of the synthesis, structural aspects and, whenever studied, functional properties of the numerous transition metal poly(5-substituted tetrazolate) frameworks appeared in the literature to the end of 2017. (C) 2018 Elsevier B.V. All rights reserved.
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