Journal
COMPTES RENDUS CHIMIE
Volume 21, Issue 12, Pages 1170-1178Publisher
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2018.05.001
Keywords
Spin crossover; Ising-like model; Nanoparticles
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Funding
- Slovak grants [APVV-14-0073, APVV-14-0078, VEGA 1/0125/18, KEGA 017STU-4/2017]
- STU Grant Scheme for Support of Excellent Teams of Young Researchers [BIOKA 1664]
- French Ministry of Higher Education, Research and Innovation
- University of Versailles
- CNRS (UMR) [8635]
- grant ANR BISTA-MAT [ANR-12-BS07-0030-01]
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The basic model for thermal spin crossover (SCO) is discussed in its microscopic and thermodynamic formulation. Compared to the basic model, its more elaborated forms formulated in course of almost 50 years are briefly reviewed with emphasis on their additional features. A separate section is devoted to the newer developments in the field of modelling of the SCO nanoparticles. The presentation of models is led in a comparative way to provide an accessible outline of the foundations of modern theoretical research on SCO and a simple applicability in quantitative interpretation of experiments. (C) 2018 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
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