Journal
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
Volume 112, Issue -, Pages 40-48Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2018.06.004
Keywords
Particle-reinforcement; Interface/interphase; Thermal properties
Funding
- Industrial Strategic Technology Development Program - Ministry of Trade, Industry & Energy (MOTIE, Korea) [10083586]
- Traditional Culture Convergence Research Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT Future Plannig [2016M3C1B5952897]
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Interfacial interaction is one of the most crucial and dominant factors affecting the performance and behavior of a material. The surfaces of layered expanded graphite (EG) were activated by covalently grafted mercapto groups (-SH), which can readily react with the macromolecular chains of rubber, thus forming a strong interfacial adhesion between the filler and the rubber matrix. Shear-induced mercapto-group-activated graphite nanoplatelets (S@GNPs) were fabricated in situ by compound mixing in a two-roll mill. A correlation between the interfacial interaction and the thermal conductivity, as well as the thermo-physical properties, was comprehensively investigated. The results showed that rubber/S@GNPs composites exhibited better mechanical performance, enhanced thermo-physical properties, and superior thermal conductivity, all of which could be attributed to the stronger interfacial interaction resulting from chemical bonding between the S@GNPs and the molecular chains of the rubber, relative to XSBR/GNP composites connected by weaker pi-pi stacking.
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