Journal
INORGANICS
Volume 3, Issue 4, Pages 448-466Publisher
MDPI
DOI: 10.3390/inorganics3040448
Keywords
coordination polymers; lanthanide; single crystal; Y-89-NMR; catalysis; domino reaction
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Funding
- EPSRC (UK) [EP/M023834/1]
- EPSRC UK National Crystallography Service at the University of Southampton
- EPSRC [EP/M023834/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/M023834/1] Funding Source: researchfish
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A systematic study was performed to further optimise the catalytic room-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere. For this purpose, a series of dinuclear lanthanide (III) coordination polymers were synthesised using a dianionic Schiff base and their catalytic activities were investigated.
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