4.4 Article

Polymerization of trimethylmethacryloyloxyethylammonium methyl sulfate in surfactant micellar solution of sodium alkyl sulfates and properties of the resultant polyelectrolytes

Journal

COLLOID AND POLYMER SCIENCE
Volume 296, Issue 5, Pages 871-881

Publisher

SPRINGER
DOI: 10.1007/s00396-018-4302-2

Keywords

Ionic monomer; Anionic surfactant; Surfactant micelle; Template polymerization; Polyelectrolytes

Funding

  1. Russian Science Foundation [16-13-10337]
  2. Russian Science Foundation [16-13-10337] Funding Source: Russian Science Foundation

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Properties of poly[trimethylmethacryloyloxyethylammonium methyl sulfate] obtained by polymerization in surfactant micellar solution of sodium dodecyl-, decyl-, and octyl sulfates were studied by viscosimetry, static, and dynamic light scattering. It was shown that the introduction of a surfactant into the polymerization medium noticeably decreases the molecular weight and polydispersity of the formed polymers as a result of kinetic and structural template effects.

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