Impact of additives on thermally-induced trans isomers in 9c,12c linoleic acid triacylglycerol

Trilinolein, with or without additives, was placed in glass ampoules and subjected to thermal treatment at 180 degrees C or 240 degrees C for 8 h. Thermal treatment of trilinolein at 180 degrees C and 240 degrees C produced twice the amount of trans nonconjugated linoleic acids (NLAs) compared to conjugated linoleic acids (CLAs), and nitrogen stream reduced the amount of both trans NLA and CLA products. The presence of additives resulted in the suppression or induction of trans NLAs and CLAs, depending on the type of additive, the concentration of the additive, and the heating temperature. Our analysis indicates that TBHQ is an effective additive for reducing trans NLA formation and inducing trans CLA formation in frying oil. Glutathione and L-cysteine at 0.1% may also be used as additives for frying oil. At suitable concentrations, Fe3+ and Al3+ ions derived from oils can reduce trans NLAs and induce trans CLAs during frying. (C) 2014 Elsevier Ltd. All rights reserved.