Journal
RSC ADVANCES
Volume 5, Issue 121, Pages 100235-100243Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra21844f
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Funding
- National Natural Science Foundation of China [61308119]
- Natural Science Foundation of Guangdong province [2015A030313]
- science and technology research program of Shenzhen [JCYJ20140509172959960, JCYJ20150331151358142]
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In this work, an on-line electrolyte spectroscopic monitoring system (OESM) is developed for long term monitoring of the electrolytes in a charge-discharge cycling VRB. We demonstrated experimentally that the transmittance spectra of the positive/negative electrolyte in a cycling VRB can be on-line monitored. With appropriate calibration, parameters such as the state of charge (SOC) of the electrolytes can be calculated. The system offers a tool for further research on the complex relationships between the spectra and the composition of the electrolyte in a VRB, and provides a dynamic method to study the kinetics of the electrolyte imbalance in VRBs.
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