Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 36, Issue 7, Pages 619-624Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201800031
Keywords
electrochemical oxidation; CH activation; hydrogen evolution; green electrolyte; lactones
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Funding
- National Natural Science Foundation of China [21390402, 21520102003]
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A synthetic protocol to lactones by electro-oxidative induced CH activation of 2-arylbenzoic acids has been developed. By using Na2SO4 aqueous solution as a cheap and green supporting electrolyte, different 2-arylbenzoic acids could provide the corresponding lactones in 30%90% yields. This reaction could be conducted on a gram scale with a good efficiency as well as a high utility for natural product synthesis.
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