Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 36, Issue 3, Pages 206-212Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201700748
Keywords
difluoromethanesulfonylation; fluoromethanesulfonylation; arenediazonium; sodium sulfinate; fluorine effect
Categories
Funding
- National Key Research and Development Program of China [2015CB931900, 2016YFB0101200]
- National Natural Science Foundation of China [21632009, 21421002, 21472221, 21372246, 21302206]
- Key Programs of the Chinese Academy of Sciences [KGZD-EW-T08]
- Key Research Program of Frontier Sciences of CAS [QYZDJ-SSW-SLH049]
- Shanghai Science and Technology program [15XD1504400]
- Youth Innovation Promotion Association CAS [2014231]
Ask authors/readers for more resources
A copper-mediated di- and monofluoromethanesulfonylation of arenediazonium tetrafluoroborates using di- and monofluoromethanesulfinate reagents provides aryl difluoromethyl (or monofluoromethyl) sulfones in good yields. It was found that the relative reactivity of these sodium fluoroalkanesulfinates in the present reactions decreases in the following order: CH2FSO2Na > CF2HSO2Na > CF3SO2Na.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
