Fabrication of a β-Bi2O3/BiOI heterojunction and its efficient photocatalysis for organic dye removal

To improve beta-Bi2O3 photocatalysis, we couple beta-Bi2O3 with BiOI to form beta-Bi2O3/BiOI heterojunctions through an in-situ treatment with hydriodic acid. The prepared heterojunctions are characterized with X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, ultra violet-diffuse reflectance spectroscopy, and X-ray photoelectron spectroscopy. Upon visible-light irradiation (lambda > 420 nm), the beta-Bi2O3/BiOI heterojunctions, especially with the molar ratio of HI to beta-Bi2O3 at 0.4, exhibit much higher photocatalytic activity than pure beta-Bi2O3 and BiOI for the degradation of methyl orange. The efficient separation of photogenerated electron-hole pairs across the interface of the heterojunction between beta-Bi2O3 and BiOI would be responsible for the enhanced photocatalytic performances. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.