4.7 Article

Thermal nitridation of triazine motifs to heptazine-based carbon nitride frameworks for use in visible light photocatalysis

Journal

CHINESE JOURNAL OF CATALYSIS
Volume 36, Issue 12, Pages 2089-2094

Publisher

SCIENCE PRESS
DOI: 10.1016/S1872-2067(15)60995-0

Keywords

Carbon nitride; Thermal nitridation; Polymerization; Photocatalysis; Hydrogen evolution

Funding

  1. National Basic Research Program of China (973 Program) [2013CB632405]
  2. National Natural Science Foundation of China [21425309, 21033003]
  3. Specialized Research Fund for the Doctoral Program of Higher Education [20133514110003]
  4. Department of Education of Fujian Province in China

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A thermal nitridation route for the assembly and polymerization of molecular triazine units to heptazine-based covalent frameworks has been successfully established. The obtained conjugated carbon nitride polymers feature nanostructures that show enhanced photocatalytic reactivity for hydrogen production under visible light irradiation. (c) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

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